Most people, myself included, usually do manual scout, at least for the snipe/cc/reflected portion of the rotation. The main thing to timing them is having a consistent tank who know when the proper time to AD is, and is always on their game for their timing, a good tank is by far the most important part to most parties, but especially a party with scouts or any other class dependent on AD/SS. Once your tank is doing AD same time every time in your groups the correct time to begin sniping sort of becomes natural.
Some tactics groups do use though, is a tank using diyce that does AD after a certain %hp left on the boss (usually around 90-85%) so you know you can begin sniping around 95% ect... Another way is to have the tank use a macro announcing the use of AD in 3 seconds, or 2 seconds, whichever you decide on, either in say or party chat.
Honestly it does take some practice, but the important part is that you are practicing with the same people, the more you switch up tanks you run with, or dps you run with, the harder it is to get use to the proper timing to snipe/cc in that particular group.